A cool rooftop lit by a clear night sky, evoking passive cooling to space

Radiative Cooling

Certain materials naturally lose heat by emitting infrared radiation through the atmosphere into the cold of space — cooling themselves without electricity, refrigerants or moving parts.

Q01
What is it?

The natural process by which surfaces emit thermal infrared radiation and cool themselves — sometimes below the surrounding air temperature.

Q02
Why does it matter?

It offers a way to cool buildings, cities and communities without electricity, refrigerants or greenhouse-gas emissions — a rare climate solution that adds nothing to warming.

Q03
Why the global interest?

A new generation of engineered materials can now cool below ambient in full sun. That opens the door to passive cooling at scale in a rapidly warming world.

Radiative Cooling Explained

A short, on-camera introduction by a working researcher in the field — the clearest starting point before we go deeper into the physics.

[ 01 · Blackbody radiation ]

Any object whose temperature is above absolute zero glows in the infrared.

Any object whose temperature is above absolute zero continuously emits thermal radiation. The warmer it is, the more it emits — and the shorter the wavelengths it emits at. This is why thermal cameras can see people in the dark: we are, quite literally, glowing.

Your skin (~310 K)
Peaks near 9 µm — right inside the atmospheric window.
A roof at midday (~330 K)
Radiates roughly 500–600 W/m² of thermal infrared upward.
The Sun (~5,800 K)
Peaks in visible light — the reason it warms surfaces on contact.
Deep space (~3 K)
The vast cold sink that any surface can, in principle, radiate toward.
Thermal image of a city showing how every surface emits infrared radiation
A thermal camera reveals what is otherwise invisible: warm surfaces glow, cool ones fade to dark.
[ 02 · Molecular origins of emission ]

Why do some materials radiate heat better than others?

Radiative cooling is not a coating trick — it is a property of the material itself. To understand why some surfaces can cool below the surrounding air while others simply bake in the sun, we have to go down to the scale of atoms and molecular bonds.

WINDOW · 8–13 µmMATERIAL SURFACE · atoms vibrate as they warmEmits in window → escapes to spaceEmits outside window → absorbed by air
Sunlight → heat → vibration → infrared

Every warm surface glows — but each material glows in its own colors.

  1. 1Sunlight strikes the surface and is absorbed by the material's atoms and molecules.
  2. 2That absorbed energy sets the atoms vibrating — stretching, bending and rotating the bonds that hold the material together.
  3. 3Vibrating charges radiate electromagnetic waves. For everyday temperatures, those waves fall in the thermal infrared.
  4. 4The exact wavelengths a material emits are set by its bonds and crystal structure. Some bonds vibrate right inside the 8–13 µm atmospheric window; others do not.
  5. 5Materials whose vibrations line up with the window can send their heat straight through the atmosphere to the cold of space. Materials whose vibrations lie outside the window lose their radiation to the atmosphere itself, which sends much of it back down.
Chemistry, not color

Why not every white surface can cool the way PDRC does.

A white wall reflects sunlight, but reflection alone is not enough. To cool below air temperature under the sun, a surface must also emit strongly in a narrow infrared band. That requires deliberate engineering of the bonds, pigments and micro-structure of the material — not just its color.

Silica & silicate glass
8–10 µm
Si–O stretching

The strong Si–O stretching vibration lies right inside the atmospheric window, which is why silica-based coatings and glass films are so widely used in engineered radiative coolers.

Ceramic oxides
8–14 µm
Metal–oxygen lattice modes

Oxides such as SiO₂, Al₂O₃ and certain perovskites have lattice vibrations that emit strongly across large portions of the window — but their solar reflectance must be engineered separately.

Polymers (PDMS, PMMA, PVDF)
7–13 µm
C–O, C–F, C–H bending

Many polymers happen to have vibrational modes inside the window. Structuring them as porous or hierarchical films boosts both reflectance and emissivity in the right bands.

Metals (aluminum, silver)
Very low emission
Free-electron reflection

Metals reflect visible light but are poor infrared emitters — a bare metal roof stays hot because it cannot radiate its heat away efficiently.

Ordinary white paint
Partial window overlap
TiO₂ + generic binder

Titanium-dioxide paints reflect sunlight well but also absorb some UV and near-infrared, and their binders emit unevenly across the window. That is why an ordinary white surface warms in the sun instead of cooling below air temperature.

Engineered PDRC coatings
8–13 µm optimized
Tuned pigment + binder system

Modern passive daytime radiative coolers combine carefully chosen pigments, porous structures and binders so the whole material system reflects >95% of sunlight and emits >95% inside the atmospheric window.

The performance of a passive daytime radiative cooler comes from the whole material system — pigments, binders, porosity and thickness working together. No single ingredient is responsible; it is the way the system is designed that determines whether a surface can quietly send its heat to space.

[ 03 · The atmospheric window ]

A wavelength range where heat can reach space.

Think of the atmosphere as a wavelength-selective filter rather than a solid barrier. Greenhouse gases absorb most of the infrared radiation Earth emits and re-radiate it in all directions — including back toward the surface. But between roughly 8 and 13 µm, atmospheric absorption is much weaker, so infrared emitted in this range travels much more directly to space. This range is what scientists call the atmospheric window.

ATMOSPHERIC WINDOW · 8–13 µm4 µm6 µm8 µm10 µm13 µm15 µm20 µm100%50%0%H₂O absorptionCO₂ absorptionATMOSPHERIC TRANSMITTANCE
Absorbed by CO₂ & H₂O

Below ~8 µm and beyond ~13 µm, greenhouse gases and water vapour absorb most outgoing thermal radiation and re-emit it in all directions.

Weakly absorbed

Between 8 and 13 µm the atmosphere transmits over 70% of upward infrared on a clear, dry day.

Humidity narrows the window

Water vapour absorbs more strongly within the 8–13 µm range, reducing net radiative heat loss. Dry, high-altitude sites are ideal; humid nights weaken the effect.

[ 04 · The two properties that matter ]

Why some materials cool better than others.

Passive radiative coolers combine two properties that rarely appear together in nature: very high reflectance across the solar spectrum — ultraviolet, visible and near-infrared — and very high thermal emissivity specifically within the 8–13 µm atmospheric window.

Solar reflectance (α_s)
> 0.95

Fraction of incoming sunlight (0.3–2.5 µm) reflected back to the sky. High reflectance stops heat before it enters the material.

Thermal emissivity (ε)
> 0.95 in 8–13 µm

Efficiency with which the surface emits thermal infrared. Tuned to the atmospheric window, that emission escapes to space.

Absorption in the window
≈ 0

The surface must not absorb infrared coming down from the atmosphere — otherwise net cooling collapses.

Net cooling power is the difference between the thermal power radiated to space and the sum of absorbed sunlight and downward atmospheric radiation. When that balance is positive, the surface cools — even in full sun.
[ 05 · Day vs night ]

Cooling day and night — the harder half is the sun.

Radiative cooling has worked at night for as long as the sky has existed. The scientific breakthrough of the last decade is doing it under direct sunlight.

Nighttime cooling
− up to 10 °C below air

With no sun to fight, any surface with reasonable infrared emissivity will radiate to the sky and cool. This is why cars, grass and rooftops can drop well below the surrounding air temperature under a clear sky — and why frost forms on clear nights above 0 °C.

Daytime cooling (PDRC)
− up to 4–9 °C below air

A passive daytime radiative cooler must reflect over 95% of sunlight while simultaneously emitting strongly in the 8–13 µm window. Recent Stanford and Columbia work has shown surfaces that cool below ambient at solar noon, with no power input at all.

[ 06 · Interactive comparison ]

Same sun. Three very different surfaces.

Under identical midday sunlight (~1,000 W/m²) and a 30 °C ambient air temperature, the choice of roof material dramatically changes surface temperature, absorbed sunlight and net cooling.

Surface
30 °C
Air 30 °C
Surface temperature
30 °C
Sunlight absorbed
5%
Net thermal emission
100 W/m²
Net cooling below air
Up to 5–8 °C below air, even at solar noon

Illustrative values based on published measurements of dark asphalt, white cool roofs, and passive daytime radiative coolers (Raman et al., 2014; Zhai et al., 2017; Mandal et al., 2018). Real-world performance depends on humidity, cloud cover and surface condition.

[ 07 · Applications ]

Where radiative cooling is already going to work.

From individual buildings to entire agricultural systems, passive radiative cooling is quietly being tested and deployed across the world. Each application shares the same starting point: reduce the heat, keep the power off.

Deployed
Buildings

Passive cool roofs and façade coatings can reduce indoor air-conditioning demand by 10–40% in hot climates.

MEER pilot
Schools

MEER's school-roof program in Freetown, Sierra Leone, is measuring indoor temperature drops in real classrooms.

Health
Hospitals & clinics

Cooler wards without extra grid load — critical in regions where refrigerated cold-chains and patient safety hinge on ambient temperature.

Emerging
Agriculture

Radiative-cooled greenhouses and shade structures can moderate crop stress during heatwaves without irrigation penalties.

Emerging
Water reservoirs

Cool coatings and covers reduce evaporation losses and thermal degradation of stored water in arid regions.

Industrial
Infrastructure

Substations, data-center roofs and industrial equipment benefit from lower surface temperatures and reduced cooling load.

Materials
Passive cooling coatings

Paints, films and fabrics engineered as retrofit surfaces — turning any existing roof, wall or tent into a radiative cooler.

R&D
Future materials

Metasurfaces, polymer nano-composites and glass-based photonic coatings are extending PDRC to more climates and surfaces.

[ 08 · MEER research ]

How MEER puts radiative cooling into practice.

MEER combines highly reflective surfaces with radiative-cooling materials on real rooftops, then measures what actually changes — surface temperature, indoor comfort, health outcomes and cooling energy use.

Researcher examining an advanced cooling material sample
MEER partners with material scientists, communities and local engineers to deploy and evaluate high-emissivity, high-reflectance surfaces at scale.
[ Keep exploring · The Science ]

Radiative cooling doesn't live in isolation.

It sits inside a wider set of physical principles that together explain how Earth manages heat — and how we can help.